A mysterious U.S. industrialist, Mr. Alexander, steals a new type of nerve gas from the U.S. Army. He leaves behind a small tablet with the number eight on it. Solo and Kuryakin investigate, with the help of Alexander's ex-wife Tracey, who seeks Alexander to sign her final divorce papers. The trio finds Alexander's parents working like slaves at a Greece rock quarry with the number five painted all around. After freeing the parents (and avoiding Alexander's thugs), they travel to a temple where they are captured by Alexander. It turns out Alexander plans to take over an Asian nation, breaking each of the Ten Commandments along the way.
Solo, Kuryakin and Tracey escape Alexander's death trap. The scene shifts to Washington and Virginia. Alexander breaks commandment No. 7 by seducing a prince's wife. He is planning on breaking No. 6 (Thou Shall Not Kill) and when that is done, his plot will be complete. Solo is menaced by a muscular thug while Kuryakin is endangered by employees of Alexander's farm in Virginia.
Thrush is developing an "ultimate computer," which, if it becomes fully operational, will mean the criminal organization even more formidable. The device is housed in a Thrush facility that uses a South American prison as a front. Kuryakin infiltrates it as a prisoner while Solo pretends to be the husband of an international prison inspector, Salty Oliver.
A magician has developed a mind-reading device and offers it to UNCLE. The problem is Thrush, led by rivals Victor Marton and Miss Belmont, also is seeking the machine.
The Re-Collectors are hunting down Nazis, who had stolen priceless art works. Solo and Kuryakin investigate and discover the situation really is more complicated.
Thrush, at a base in the Middle East, is developing a "vaporizer," which dissolves almost any object. Kuryakin tries to enlist the assistance of a tribe of Arabs to help. Solo, meanwhile, convinces a soon-to-be retired Thrushman that he'll live longer if he switches sides.
The search for a volcano-activating device takes Napoleon Solo (Robert Vaughn) and Illya Kuryakin (David McCallum) to Japan, where they must find Thrush's Far East headquarters.
Mr. Robspierre, a descendant of the original Robspierre, plans to launch a nuclear missile and destroy France's vineyards. By doing so, he hopes to restore the virtue of France. Solo works to protect the daughter of a scientist Robspierre abducted while Kuryakin infiltrates Robspierre's operation.
Solo and Kuryakin, aboard the Adriatic Express from Vienna to Venice, are seeking a Thrush chemical that can end the reproductive process in life forms. We meet Madame Nemirovitch, who claims to be the founder of Thrush.
El Supremo, the corrupt ruler of a Caribbean nation, abducts an opposition leader who had been under the protection of U.N.C.L.E. Solo and Kuryakin travel to El Supremo's country to free the opposition leader and bring down El Supremo.
Thrush is conducting an operation using a mortuary as a front. One Thrushman appears to commit suicide. Another is falling for the "dead" man's girlfriend. UNCLE is using the girlfriend, whose name is Jojo Tyler and the "dippy blonde" of the episode title, to break the operation.
Thrush wipes out UNCLE's Geneva station with a strain of small, almost invisible, killer bees. The criminal organization next wants to use the bees on UNCLE's New York headquarters.
Thrush has a mole inside UNCLE's New York headquarters. All signs point to George Dennell, a good-natured UNCLE employee who envies enforcement agents such as Solo and Kuryakin. Dennell protests he is innocent and Solo takes a big chance on George.
A scientist has developed a machine that reverses the aging process. UNCLE races Thrush for the device. An aging British politician and his manipulative wife will be key players in the outcome.
A British politician's career is suddenly rejuvenated after he's been exposed to a device that reverses the aging process. But he's also a prisoner. He needs additional treatments and the machine is now under the control of Thrush and the politician's manipulative wife.
Kuryakin, who has photographed Thrush codes needed by UNCLE, is captured by the criminal organization. He parachutes, with a stewardess, from a chartered aircraft over the North African desert. They end up at a Foreign Legion post, still manned by Basil Calhoun, who doesn't know the legion has been disbanded. Both Solo and Thrush are trying to get to Kuryakin.
After Solo and Kuryakin are sidelined, Waverly turns to two agents: April Dancer, a young woman, and Mark Slate, a veteran operative who, it turns out, is older than 40, the retirement age for enforcement agents.
The title refers to criminal Rafael Delgado, an expert diamond thief. He's involved with a band of criminals, who dress in British style (bowler hats and umbrellas) but who speak Italian. It's implied they are Mafia types trying to pass themselves off as British. Delgado, even while in prison, has pulled off a stunning robbery with the help of the gang. So many diamonds are missing it could affect the world's economy.
Thrush mistakes Buzz Conway for a scientist. Solo and Kuryakin use that to their advantage while trying to smash a Thrush operation headed by Marvin Elom. Narcissus Darling, a Thrush femme fatale, also is involved.
Count Zark, a Thrush agent, operates out of Transylvania and has developed a worldwide menace involving bats. Meanwhile, UNCLE is checking out a young woman who seems capable of reading the minds of others. Solo and Kuryakin discover how both events are related.
Professor Lillian Stemmler is collaborating with Thrush. She has developed two formulas: Plus X, which heightens the senses, and Minus X, which temporarily transforms people into child-like morons. Thrush intends to use both to steal U.S. military secrets.
Thrushman L.C. Carson has kidnapped Chief Highcloud of the Cardiac tribe of Indians in Oklahoma. The criminal organization also is menacing the chief's daughter, Charisma, who dances in New York. It turns out Thrush is working on a hydrogen bomb on the Cardiac reservation. Solo leads a group of Indians, all riding motorcycles, in a climatic fight with the Thrush forces.
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