- Roger Moore
- Self - Host / James Bond
- Ken Adam
- Self
- Michael Apted
- Self
- Vic Armstrong
- Self
- David Arnold
- Self
- John Barry
- Self
- Honor Blackman
- Self / Pussy Galore
- Samantha Bond
- Self / Miss Monneypenny
- Pierce Brosnan
- Self / James Bond
- Ray Brown
- Self
- John Cleese
- Self / R
- Andrew Collins
- Self
- Sean Connery
- Self / James Bond (archive footage)
- Chris Corbould
- Self
- Diana Coupland
- Self
- Simon Crane
- Self
- Judi Dench
- Self
- Sarah Donohue
- Self
- Shirley Eaton
- Self / Jill Masterson
- Britt Ekland
- Self / Mary Goodnight
- Ken Follett
- Self
- Fiona Fullerton
- Self
- Eunice Gayson
- Self / Sylvia Trench
- Lewis Gilbert
- Self
- John Glen
- Self
- Goldie
- Self
- Michael Grade
- Self
- Guy Hamilton
- Self
- Nigel Havers
- Self
- Eamonn Holmes
- Self
- Peter R. Hunt
- Self
- Eddie Izzard
- Self
- Millie Kendall
- Self
- Richard Kiel
- Self / Jaws
- James King
- Self
- Burt Kwouk
- Self / Spectre 3
- George Lazenby
- Self / James Bond
- Christopher Lee
- Self / Scaramanga
- Bert Luxford
- Self
- Shirley Manson
- Self
- Paul Morley
- Self
- Barry Norman
- Self
- Tara Palmer-Tomkinson
- Self
- Colin Paterson
- Self
- Jonathan Pryce
- Self / Elliot Carver
- Greg Rusedski
- Self
- Mark Seaman
- Self
- Jane Seymour
- Self / Solitaire
- Nick Sullivan
- Self
- Rick Sylvester
- Self
- Michael G. Wilson
- Self
- B.J. Worth
- Self
- Terence Young
- Self
- Ursula Andress
- Honey Rider
- Claudine Auger
- Domino
- Barbara Bach
- Major Anya Amasova / Agent XXX (archive footage) (uncredited)
- Joe Don Baker
- Jack Wade
- Kabir Bedi
- Gobinda
- Daniela Bianchi
- Tatiana Romanova
- Michael Billington
- Sergei Barsov
- Emily Bolton
- Manuela
- Adolfo Celi
- Largo
- Lois Chiles
- Dr. Holly Goodhead
- Maria Grazia Cucinotta
- Cigar Girl
- Timothy Dalton
- James Bond
- Robert Davi
- Franz Sanchez
- Gabriele Ferzetti
- Draco
- Gert Fröbe
- Auric Goldfinger
- Serena Gordon
- Caroline
- Walter Gotell
- General Gogol
- Mie Hama
- Kissy Suzuki
- Julius Harris
- Tee Hee
- Teri Hatcher
- Self
- Famke Janssen
- Xenia Onatopp
- Gottfried John
- Self
- Louis Jourdan
- Kamal Khan
- Curd Jürgens
- Carl Stromberg
- Geoffrey Keen
- Minister of Defence
- Yaphet Kotto
- Mr. Big / Dr. Kananga (archive footage) (uncredited)
- Bernard Lee
- M
- Lotte Lenya
- Rosa Klebb
- Cec Linder
- Felix Leiter
- Desmond Llewelyn
- Q
- Philip Locke
- Vargas
- Michael Lonsdale
- Hugo Drax
- Carey Lowell
- Pam Bouvier
- Tania Mallet
- Tilly Masterson
- Zena Marshall
- Miss Taro
- Lois Maxwell
- Miss Moneypenny
- Margaret Nolan
- Dink
- Donald Pleasence
- Blofeld
- Denise Richards
- Dr. Christmas Jones
- Diana Rigg
- Tracy Vincenzo
- Harold Sakata
- Oddjob
- Izabella Scorupco
- Natalya Simonova
- Angela Scoular
- Ruby
- Robert Shaw
- Red Grant
- Vladek Sheybal
- Kronsteen
- Teru Shimada
- Mr. Osato
- Madeline Smith
- Beautiful Girl
- Ilse Steppat
- Irma Bunt
- Tetsurô Tanba
- Tiger Tanaka
- Francoise Therry
- Chew Mee
- Cecilie Thomsen
- Professor Inga Bergstrom
- Hervé Villechaize
- Nick Nack
- James Villiers
- Tanner
- Akiko Wakabayashi
- Aki
- Jan Werich
- Blofeld (unused Stills from You Only Live Twice)
- Joseph Wiseman
- Dr. No
- Michelle Yeoh
- Wai Lin
