Episode list

ChemicalForce

Azides: Sodium Azide NaN3 and Lead Azide Pb(N3)2
Felix ignites sodium azide which decomposes to sodium metal which itself ignites leaving behind the still quite reactive chemical sodium peroxide. He does a similar demonstration with lead azide which was loaded into the hollow point bullets used in the assassination attempt on Ronald Reagan.
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Hot 5 chemical reactions from subscribers
Felix performs five reactions requested by his viewers. Needless to say, the reactants are pretty reactive in any situation and some are rather uncommon. But what these reactions all share is a penchant for combustion in flames or explosion..
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Episode dated 21 June 2018
Felix attempts to react red phosphorus with hot water as Walter White did in "Breaking Bad" to escape from gangsters. No reaction. He should have used a metal phosphide. So Felix cooks up some magnesium phosphide which he reacts with water to generate the desired toxic phosphine gas.
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SOCl2: Thionyl chloride
Thionyl Chloride is a colorless acrid liquid that hydrolyzes to sulfur dioxide and hydrochloric acid. Felix reacts cobalt (II) chloride hexahydrate which changes from pink to blue as the water is consumed by the thionyl chloride. He also demonstrates highly exothermic reaction of thionyl chloride with various metals.
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B2H6: Diborane. Synthesis and burning
Felix prepares diborane in a simple test tube reaction of sodium borohydride and stannous chloride. The reaction begins in the solid state but becomes vigorous when the reactants are heated to melting. Felix doesn't try to isolate the diborane but ignites the vapors to show a green flame.
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NOClO4: Nitrosyl perchlorate
Since it's not commercially Felix prepares nitrosyl perchlorate by the established method of reacting nitrogen oxides with perchloric acid. If it sounds like nitrosyl perchlorate is a reactive chemical, it is, so now the fun begins. It reacts explosively with organic compounds with oxygen functional groups and the more reactive metals.
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Sm: Samarium element, chemical reactions
Samarium is a reactive lanthanide metal the oxidizes in air and reacts slowly with water. Felix finds it is highly reactive with oxygen, the halogens chlorine, bromine and iodine, the superoxides of barium and potassium and dinitrogen trioxide to the point of combustion.
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CS2: Carbon disulfide. Chemical reactions
Felix spares us the barking dogs experiment to do some real carbon disulfide chemistry. He synthesizes sodium ethyl xanthogenate and from it precipitates the copper salt He demonstrates the brilliant blue flame of burning sulfur dissolved in carbon disulfide and the spontaneous combustion of chlorine dioxide in carbon disulfide.
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Five Random Chemical reactions
Felix performs five quick reactions mostly in the solid state: zirconium powder with frozen sulfur hexafluoride, strontium powder with strontium nitrate, germanium powder with chlorine gas, and lithium borohydride with both Chromyl chloride and potassium peroxide. Things get hot.
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Re2O7: Rhenium Heptoxide. Chemical reactions
Rhenium heptoxide is a rare and expensive yellowish green compound. It sublimates at low temperature condensing into a liquid before recrystallizing. Although a weak oxidizer it readily reduces hydrobromic acid to bromine. Felix demonstrates various other redox reactions of the chemical. often with colorful products.
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H2Se: Hydrogen selenide. Red selenium
Molten selenium reacts with the more reactive metals such as sodium, potassium and aluminum, to produce the selenide salts. Reacting them with a strong acid produces hydrogen selenide. The selenides can also be reduced to produce red selenium.
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TiH2: Titanium (II) Hydride. Solid Hydrogen Solution
Titanium dihydride is a gray, non-stoichiometric compound that is never quite 1:2. It grows darker as it absorbs hydrogen. Ironically although titanium powder and hydrogen are highly flammable the hydride is much less so. But Felix can't resist mixing in a little perchlorate to start some fireworks.
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Interhalogen Compound: ICl3 Iodine Trichloride
Iodine trichloride is a yellow fuming solid that thermally decomposes to iodine monochloride and chloride. Flexic reacts this compound with sulfuric acid, potassium hydroxide, tin II chloride, red phosphorus, lithium borohydride, hydrazine and decaborane. Many of the solid mixtures spontaneously ignite.
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Rubidium ampoule opened in Air for chemical reactions
Felix has acquired some costly samples of rubidium. Of course it reacts with water but it is surprisingly resistant to even pure oxygen or ozonated oxygen. Iodine trichloride, oleum and, with a little 'compression', boron tribromide, are much more accommodating. Felix loses a couple watch glasses when rubidium reacts a little to vigorously with iodine and bromine.
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Ozonides! Potassium and Cesium Ozonides. KO3, CsO3
As potassium and cesium hydroxide and potassium superoxide are exposed to ozone the reactant becomes yellow then red as the ozonides are produced. The ozonides decompose as they warm sometimes explosively. Felix also reacts potassium with ozone after first dissolving the metal in liquid ammonia.
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Liquid ammonia and Chromium(III)Oxide. NH3 + Cr2O3
Felix is determined to burn ammonia. A direct flame doesn't work so lets try some chromium compounds. Potassium dichromate burns easily on it's own but ammonia won't make it burn. Ammonia won't even burn with the resultant hot chromium(III) oxide. What about potassium chlorochromate?
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Molybdenum Pentachloride. MoCl5: Chemical Reactions
Moylbdenum pentachloride is a black solid. Felix reacts it with air, water and hydrochloric acid to produce various oxychlorides in a rainbow of colors. He demonstrates a clever way to collect dichlorodioxomolybdenum from a test tube. For the finale a solid state hypergolic reaction with lithium borohydride.
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Phosphorus pentabromide: PBr5. Chemical reactions
Phosphorus pentabromide is a brilliant yellow solid that thermally decomposes to phosphorus tribromide and bromine. Felix reacts phosphorus pentabromide with potassium superoxide and red phosphorus with explosive results. It readily dissolves in carbon disulfide.
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GeH4: Germane. Highly flammable & Toxic gas!
German is synthesized by the reaction of lithium aluminum hydride with germanium tetrachloride. The formation of germane gas is demonstrated by the reaction with silver nitrate to produce silver germanide. Felix creates a germanium mirror on the inside of a glass tube by the thermal decomposition of germane.
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That's how liquid ozone explodes!
Ozone is an intense blue, unstable triatomic allotrope of oxygen that explosively decomposes to diatomic oxygen as Felix demonstrates. He produces his ozone with a handy dandy ozone generator and then performs several chemical reactions that serve as qualitative tests for the chemical.
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Iron pentacarbonyl. Fe(CO)5 photolysis. Extra Pure Iron!
Iron pentacarbonyl is an effect reducing agent because the iron is readily available in its neutral state as Felix demonstrates with several oxidixed metals. He also demonstrates its photolysis to diiron-nonacarbonyl using a laser to make the reaction easily visible.
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Interhalogen compound: IBr Iodine monobromide
Iodine monobromide is a solid resembling iodine but it releases red fumes rather than violet. In the molten state it is a deep red liquid. Felix reacts this reagent with sulfuric acid, potassium hydroxide, hydrazine, potassium, copper, red phosphorus, antimony and aluminum. The more energetic reactions produce copious red vapors and some reaction occur in the solid state.
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That's how Gallium is afraid of Bromine
After melting some gallium Felix plays with gallium droplets in water and liquid nitrogen which we see in glorious slow motion. Then it's time for chemistry as gallium reacts with bromine appearing to gobble it up like a living creature. It even reacts to bromine vapor.
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Iodine monochloride. Interhalogen compound can dissolve Gold
Iodine-monochloride is a fuming dark red liquid with yellow vapor. Felix displays extensive footage, some in slow motion, of its reaction with titanium, sodium, calcium, antimony, sodium hydroxide, nitric acid, and gold. Generally iodine is produced and if the reaction is particularly exothermic, purple iodine vapor.
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Thiophosgene. Sulfur Analogue of Phosgene
Thiophosgene is really dangerous. It come in a glass bottle, wrapped in plastic packed in a vermiculite in a can. But it readily undergoes a variety of interesting reactions which Felix demonstrates despite the risk
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Violet Violent Phosphorus Explodes on impact!
Violet phosphorus explodes on impact, as Felix demonstrates. So you might expect it to be more reactive than red phosphorus. But while both red and violet phosphorus react with chlorine, only the red allotrope reacts with bromine.
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